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121.
In this paper, one- and two-photon absorption properties as well as the transition nature of a series of donor-π-acceptor-type compounds with trivalent boron as an acceptor have been theoretically studied by using INDO/SDCI method. Our calculations indicate that the four o-methyl moieties on the two mesityl groups play an important part in protecting the trivalent boron from being attacked by oxygen in the air. The trivalent boron containing group can be an all-right electron-acceptor with some bulky groups attached to it. On the basis of geometry optimization and UV–vis spectra, the positions and strengths of two-photon absorption for these molecules were reported. 相似文献
122.
A. Alvarez F. R. Romero J. F.R. Archilla J. Cuevas P. V. Larsen 《The European Physical Journal B - Condensed Matter and Complex Systems》2006,51(1):119-130
We study the dynamics of moving discrete breathers in an interfaced piecewise DNA molecule.
This is a DNA chain in which all the base pairs are identical and
there exists an interface such that the base pairs dipole moments at each side are oriented in opposite
directions.
The Hamiltonian of the Peyrard-Bishop model is augmented with a
term that includes the dipole-dipole coupling between base pairs.
Numerical simulations show the existence of two dynamical regimes.
If the translational kinetic energy of a moving breather launched
towards the interface is below a critical value, it is trapped in
a region around the interface collecting vibrational energy. For
an energy larger than the critical value, the breather is
transmitted and continues travelling along the double strand with
lower velocity. Reflection phenomena never occur.
The same study has been carried out when a single dipole is oriented
in opposite direction to the other ones.
When moving breathers collide
with the single inverted dipole, the same effects appear. These
results emphasize the importance of this simple type of local
inhomogeneity as it creates a mechanism for the trapping of
energy.
Finally, the simulations show that, under favorable conditions,
several launched moving breathers can be trapped successively at the interface
region producing an accumulation of vibrational energy. Moreover,
an additional colliding moving breather can produce a saturation
of energy and a moving breather with all the accumulated energy
is transmitted to the chain. 相似文献
123.
124.
In the present study a methodology for TOF-S-SIMS measurements is developed to gain information on the distribution of molecules on and in polymer coatings (thickness ∼100 μm). Experiments were carried out on model systems consisting of one or more additive-containing polyvinylbutyral coatings. Several organic additives were selected: carbocyanine dyes, basonyl blue and the pharmaceutical risperidone. The additives have been measured as pure compounds on a Si substrate to obtain good reference spectra. After optimisation of the sample preparation method, the coatings were embedded in epoxy resin and stored in an oven (60 °C) for 24 h. Cross-sections were made by means of a microtome. S-SIMS spectra were taken on the prepared cross-sections before and after Au was deposited on the sample surface. Compared to the untreated samples, the Au covered samples give rise to more intense secondary ion signals. Generally, signals of the intact cations were more intense than those of the fragment ions. Apart from mass spectra, images of the additive distribution in the coatings could also be acquired by recording structural ion signals. It was possible to make secondary ion images of the additive molecule ions with a (sub)-micrometer lateral resolution. 相似文献
125.
B. Mukeru 《中国物理C(英文版)》2023,47(2):024104-024104-5
An analysis of the breakup of the \begin{document}$ ^{31}{\rm Ne} $\end{document} ![]()
![]()
weakly-bound neutron-halo system on a lead target is presented, considering the \begin{document}$ 2p_{3/2} $\end{document} ![]()
![]()
and \begin{document}$ 1f_{7/2} $\end{document} ![]()
![]()
ground-state configurations. It is shown that a high centrifugal barrier almost wipes out the breakup channel, thus assimilating the breakup of a weakly-bound system to that of a tightly-bound system, and also reduces the range of the monopole nuclear potential. Consequently, a high centrifugal barrier prevents the suppression of the Coulomb-nuclear interference (CNI) peak by weakening couplings to the breakup channel and reducing the range of the monopole nuclear potential, two main factors that would otherwise suppress such a peak. The present study also identifies couplings to the breakup channel and a long-ranged monopole nuclear potential as the main factors that lead to the suppression of the CNI peak. A low centrifugal barrier together with a Coulomb barrier would also effectively prevent the suppression of the CNI peak in proton-halos as reported in the case of the \begin{document}$ ^8{\rm B} $\end{document} ![]()
![]()
proton-halo. 相似文献
126.
提出沿构件长度方向截面尺寸发生缓慢变化时双帽箱型横截面点焊薄壁构件扭转特性的分析方法,并利用此方法讨论了变截面等焊点间隔构件和变截面非等焊点间隔构件的翘曲扭转问题并得到如下结论:①变截面构件长度越长,扭转刚度越小,其刚度下降率与等截面构件几乎相等;②采用变截面构件,不仅保持一定刚度,还可以减少焊点数目,降低焊接成本;③若右半部分的焊点间隔p2对左半部分的焊点间隔p1的变化范围小于25%,则其传递剪力变化不大。仿真结果与实验值以及利用cosmos/m而得到的数值解相比较吻合得较好,完全满足工程精度要求。此研究为解决实际车体结构的设计问题,具有有益的参考价值。 相似文献
127.
V. I. Gulyaev P. Z. Lugovoi M. A. Belova I. L. Solov’ev 《International Applied Mechanics》2006,42(6):692-698
The quasistatic stability of a rotating drillstring under longitudinal force and torque is analyzed. Constitutive equations
are derived, and a technique to solve them is proposed. It is shown that the buckling mode of the drillstring is helical within
a section subjected to compressive forces
__________
Translated from Prikladnaya Mekhanika, Vol. 42, No. 6, pp. 101–109, June 2006. 相似文献
128.
圆形截面是工程中常使用的截面形式之一,但圆形截面的配筋计算较为困难,存在双重非线性(材料和截面宽度变化的非线性),《混凝土结构设计规范》给出了计算均匀配筋的超越方程组,且须迭代求解,无法手算.另外,一些圆形截面构件(如桥墩、桩基的预制桩和灌注桩等)的截面尺寸大,构件长,钢筋用量大,若采用均匀布置的配筋方式,中性轴附近的钢筋应力小,强度利用率低,经济性差.若采用非均匀配筋,在远离中性轴的外围区域布置受力钢筋,可大幅节省钢筋用量,且能充分利用钢筋及混凝土的强度.为此本文通过应变计算应力,再计算出内力的方法推导计算圆形截面配筋的公式,并将计算结果绘制成了能计算配筋的无量纲诺模图,由此可快速手算配筋,该图通用性强,可用于任意直径大小及C50以下的混凝土强度等级,是一能快速计算配筋的实用工具. 相似文献
129.
Hyung-gyu Jun Thomas R. Way Bjrn Lfgren Mats Landstrm Alvin C. Bailey Eddie C. Burt Timothy P. McDonald 《Journal of Terramechanics》2004,41(4):209-222
A Trelleborg Twin 421 Mark II 600/55-26.5 steel-reinforced bias-ply forwarder drive tire at inflation pressures of 100 and 240 kPa and dynamic loads of 23.9 and 40 kN was used at 5% travel reduction on a firm clay soil. Effects of dynamic load and inflation pressure on soil–tire contact pressures were determined using six pressure transducers mounted on the tire tread. Three were mounted on the face of a lug and three at corresponding locations on the undertread. Contact angles increased with decreases in inflation pressure and increases in dynamic load. Contact pressures on a lug at the edge of the tire increased as dynamic load increased. Mean and peak pressures on the undertread generally were less than those on a lug. The peak pressures on a lug occurred forward of the axle in nearly all combinations of dynamic load, inflation pressure, and pressure sensor location, and peak pressures on the undertread occurred to the rear of the axle in most of the combinations. Ratios of the peak contact pressure to the inflation pressure ranged from 0 at the edge of the undertread for three combinations of dynamic load and inflation pressure to 8.39 for the pressure sensor on a lug, near the tire centerline, when the tire was underinflated. At constant dynamic load, net traction and tractive efficiency decreased as inflation pressure increased. 相似文献
130.
由地质作用影响形成的易出险堤段称为地质险段 ,主要包括活断层作用影响形成的堤基易渗漏段、强地震高发区段和地基稳定性差段等。构造节点是识别地质险段的重要的河流地貌标志之一。根据成因 ,本文将黄河下游的地质险段分为三类 ,即新构造险段、沉降险段、断裂复活险段。针对黄河下游堤防地质特征 ,圈定出东坝头、大刘屯—董口黄河南岸和路那里—十里堡黄河南岸地质险段 ,提出了治理的有关措施 相似文献